Here is a visual guide to HazCom pictograms from OSHA: ANATOMY OF A GHS CHEMICAL LABEL. Chemical hazards for the updated HCS have … This can be tricky because if … Each pictogram features a black graphic on a white background, with a red border. Oxidizers may cause a fire by increasing the concentration of oxygen in the air. 3�:�y9^O���d��8�}���T@��\50��B1���y�Ar巇�uc�=�e@���!�u �S�����=�8�6�ϋ ����b&���D��sS����䕊&8��'7z��U�}ޓLܐ�h�$367e44L�Z���ΰ!�5�!8���w�7ɧ� The following pictograms are included in the UN Model Regulations but have not been incorporated into the GHS because of the nature of the hazards. The GHS transport pictograms are the same as those recommended in the UN Recommendations on the Transport of Dangerous Goods, widely implemented in national regulations such as the U.S. Federal Hazardous Materials Transportation Act (49 U.S.C. Flame over Circle This symbol on a chemical label means that the substance is an oxidizer. Concise and easy to read information is the epitome of visual communication, and pictograms do just that. %PDF-1.3 There are many national and international sources for chemical hazard classifications. The National Industrial Chemical Notification and Assessment Scheme … Hazard pictograms form part of the international Globally Harmonized System of Classification and Labelling of Chemicals (GHS). With a quick glance, you can see, for example, that the product is flammable, or if it might be a health hazard. Each pictogram consists of a symbol on a white background framed within a red border and represents a distinct hazard(s). It has still to be implemented by the European Union (CLP regulation) in 2009. Once the classification of a chemical has been determined, standard signal word, hazard pictograms, hazard statements and precautionary statements … Label Requirements Labels, as defined in the HCS, are an appropriate group of written, printed or graphic informational elements concerning a hazardous chemical that are affixed to, printed on, or attached to the immediate container of a hazardous chemical, or to the outside packaging. With a quick glance, you can see, for example, that the product is flammable, or if it might be a health hazard. Some may start fires, cause explosions, or damage the environment. Because of their dangerous nature, safety and health laws require suppliers and workplaces to label and attach information about all hazardous products. Match the ategory to the Label Area A. Note: The asterisks are replaced by the class number and compatibility code, Explosives – Substances and articles which are classified as explosives but which present no significant hazard, Note: The asterisk is replaced by the compatibility code, Explosives – Very insensitive substances which have a mass explosion hazard. Pictogram Symbol Pictogram Name Hazards General Meaning Flame Flammable Pyrophoric Self-heating Emits Flammable Gas burn. Pictograms can detail the level of a hazard’s physical risks, chemical risks, environmental risks, and health risks. However chemical containers that are ONLY used within the facility are somewhat of a gray area when it comes to OSHA HazCom. 100–185. NFPA/HMIS labels can be used for workplace chemicals IF the employee is trained as if they had access to the full GHS-compliant label. The product identifier for Methanol is “Methanol.” The GHS-compliant label for mixtures must include all components of the mixture with their relative percentages. Most pictograms have a distinctive red "square set on one of its points" border. liquid nitrogen, liquid oxygen, liquid helium, Self-reactive substances and mixtures, type G (see, Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3, e.g. J���b�4D0. Information Sheet Page 1. Hazard Labelling & Packaging according to the CLP Regulation Information Sheet Labelling of Hazardous Substances/Mixtures: A hazard label must contain the following elements applicable to the substance or mixture placed on the … Pictograms. The ADG Code prescribes mandatory minimum sizes for ADG labelling elements, which must be complied with when preparing labels to meet both WHS and ADG requirements. True False 13. Pictograms are assigned to specific … There are a total of nine different pictograms, each representing a different type of hazard. In total, there are nine GHS pictograms that identify risk in three categories: Physical, health, and environmental. The HCS requires chemical … More than 65 countries are using the GHS system or are currently in the process of adopting it, resulting in enhanced transparency in chemical safety use and shipping. The CLP label should be firmly affixed to one or more surfaces of the packaging immediately containing your substance or mixture. Note that these requirements … The CLP Regulation has introduced a new classification and labelling system for hazardous chemicals in the European Union. Two sets of pictograms are included within the GHS: one for the labelling of containers and for workplace hazard warnings, and a second for use during the transport of dangerous goods. Some key resources include: 1. The 6 Main Elements of a GHS Label GHS-compliant labels contain six main elements. The pictograms OSHA has adopted improve … True False 12. A chemical label does not need to have a 24-hour emergency phone number on it. Pictograms and label text should be clear and easily readable. In those situations, paragraph (f)(5) provides that each container of hazardous chemicals leaving the workplace must be labeled in a way that does not conflict with the requirements of the Hazardous Materials Transportation Act, 49 … Most pictograms have a distinctive red, diamond-shaped border. `z�6��f How to Choose GHS Pictograms for A Chemical? True False 11. The pictograms have also … In total, there are nine symbols that can … The picto-gram on the label is determined by the chemi-cal hazard classification. The publication of the final Hazardous Products Regulation (HPR) by the Federal Government on February 11, 2015, commenced the alignment of Canadas Workplace Hazardous Materials Information System (WHMIS) with the UNs internationally agreed-upon system, the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Hazard pictograms form part of the international Globally Harmonized System of Classification and Labelling of Chemicals (GHS). Each hazard pictogram shall cover at least one fifteenth of the surface area of the harmonised label but the minimum area shall not be less than 1 cm2. Which pictogram is not required by OSHA? pictograms on labels to alert users of the chemical . It is important to always read the label on a product, even if you have used the product many times … �i�+?Q"��źn>!����������,�؍^�Ŵ �6���!j��G�%0⟉�?&��^:`�P�F������+�BݢD�49���i�p�b���׌��'�ZNc�#X�Mwdi�a�[ �I�O6y�pW����T(\���h��� 2��)Q�����aE���. ��fMj1ߌ�W�z�n����z��.J���Ű*m'��b��Yx�Im�^/���]�AZ ��Y(̨�H��r�M�ܒ|s%=��U��zAa!-����|=H��>��u�ڝg���8*/ p�- �-�Z@�tA�+�7���:��ڸ�*�M�t�c�%9I}���D�/�d �e`���5 ,�{�ƨ�a�O�e>W!c�yChx�զ�����k��=���pFA�4B�����H�ܐ���DN0 The pictograms for labelling chemical products have changed. a label, and describes what pictograms are and how to use them. Flammable gases – Gases which at 20 °C and a standard pressure of 101.3 kPa: Non-flammable non-toxic gases – Gases which: Flammable liquids – Liquids which have a flash point of less than 60 °C and which are capable of sustaining combustion, Flammable solids, self-reactive substances and solid desensitized explosives – Solids which, under conditions encountered in transport, are readily combustible or may cause or contribute to fire through friction; self-reactive substances which are liable to undergo a strongly exothermic reaction; solid desensitized explosives which may explode if not diluted sufficiently, Substances liable to spontaneous combustion – Substances which are liable to spontaneous heating under normal conditions encountered in transport, or to heating up in contact with air, and being then liable to catch fire, Substances which in contact with water emit flammable gases – Substances which, by interaction with water, are liable to become spontaneously flammable or to give off flammable gases in dangerous quantities, Oxidizing substances – Substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material, Organic peroxides – Organic substances which contain the bivalent –O–O– structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals, Toxic substances – Substances with an LD50 value ≤ 300 mg/kg (oral) or ≤ 1000 mg/kg (dermal) or an LC50 value ≤ 4000 ml/m3 (inhalation of dusts or mists), e.g. Pictograms are graphic images that immediately show the user of a hazardous product what type of hazard is present. Hazard pictograms are the shape of a square set at a point (diamond shape), and must have a black symbol on a white background with a red border (section 1.2.1 of Annex I to CLP). requires pictograms on labels to alert users of the chemical hazards to which they may be ex-posed. For example, the label for a mixture containing ingredients with unknown toxicity in amounts higher than or equal to 1% must include a statement indicating the percent of the ingredient or ingredients with unknown toxicity. hazards to which they may be exposed. A hazard pictogram is an image on a label that includes a warning symbol and specific colours intended to provide information about the damage a particular substance or mixture can cause to our health or the environment. Label Requirements Labels, as defined in the HCS, are an appropriate group of written, printed or graphic informational elements concerning a hazardous chemical that are affixed to, printed on, or attached to the immediate container of a hazardous chemical, or to the outside packaging. There are 9 standardized pictograms, each representing a different hazard. Each pictogram consists of a symbol on a white background framed within a red border and represents a distinct hazard(s). Inside this border is a symbol that represents the potential hazard (fire, health hazard, corrosive, etc.). Supplier Information— Name, address and telephone number of the chemical manufacturer or im- porter . The arrangement on the label. Supplemental label information – some supplemental label information is required based on the classification of the product. 6. In many cases, these containers will also be the hazardous chemical's immediate container, and therefore, both a DOT and an HCS label are required. The final Hazard Communication Standard (HCS) requires eight of these pictograms, the exception being the environmental pictogram, as environmental hazards that are not within OSHA’s jurisdiction. By clicking the picture below, you can download GHS pictograms in one click and edit them freely. Some chemicals need more careful handling than others. As long as the label has the Signal Word on it, it doesn’t need to have a pictogram too. HCS Pictograms and Hazards. Chemicals come in many forms and can cause death, cancers, respiratory, organ damage, and birth defects, if misused. Labels carry the product name, … Lists of classified substances like the Hazardous Chemical Information System are not mandatory under the model WHS Regulationsand should be used for guidance only. Exploding Bomb … Learning about each of them is essential for anyone working with or around hazardous chemicals. A square red frame set at a point without a hazard symbol is not a pictogram and is not permitted on the label. A set of standardized pictograms is used by WHMIS on product labels and data sheets to easily show the user of a hazardous product what type of hazard is present.These hazard images convey meaning quickly and accurately for workers. The product identifier is most often the common product name of the chemical, and must match the product identifier on the SDS. nearly everything that contains cyanide groups. x��O��q���)�|sμ6�&���Jۑ%�3��E��=�X�G��Q�ğ3����w�@��=9��9�! The GHS chemical hazard pictograms are intended to provide the basis for or to replace national systems of hazard pictograms. Pictograms are symbols used to warn you about chemical hazards. You have to determine the hazard class and hazard category of a chemical first. A single label may contain one or multiple pictograms depending on the hazards presented by the chemical. are asphyxiant – gases which dilute or replace the oxygen normally in the atmosphere; or, are oxidizing – gases which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does; or, are known to be so toxic or corrosive to humans as to pose a hazard to health; or, are presumed to be toxic or corrosive to humans because they have an LC, cause full thickness destruction of intact skin tissue on exposure time of less than 4 hours; or, exhibit a corrosion rate of more than 6.25 mm per year on either steel or aluminium surfaces at 55 °C, This page was last edited on 18 February 2021, at 15:10. The label may be larger than indicated above, e.g. Self-reactive Organic peroxides These chemicals burn or can release gases that Flame over Circle Oxidizers These chemicals give off oxygen and can make a fire spread. Labels may also include … Two sets of pictogramsare included within the GHS: one for the labelling of containers and for workplace hazard warnings, and a second for use during the transport of dangerous goods. %��������� Health Hazard • Carcinogen • Mutagenicity • … Either one or the other is chosen, depending on the target audience, but the two are not used together. There are nine pictograms under the Globally Harmonized System (GHS) to convey health, physical and environmental hazards. Hazardous chemical labels may require more than one pictogram. �W� )ce�9��|ܨE����ΚFzQb�6(:*��m�������ii�>�g��B�{���$jE�m�"}Y4KZ�L��f����%v�X�)&,I�:B�MX~I��f}E:5�b�,���L�� ��U^�S��6ӫ�YF6���'D�nނ3�6^ΒeY��be�G��ۨ ���[���(^� It is the classification criteria that are mandatory. << /Length 6 0 R /Filter /FlateDecode >> stream They should be legible horizontally when the package is set down normally.A CLP compliant label shall contain the following elements (See our sample CLP label illustration here): 1. the name, address and telephone number of the supplier/s of the substance or mixtur… [1] The two sets of pictograms use the same symbols for the same hazards, although certain symbols are not required for transport pictograms. True False 14. Together, the symbol and the border are referred to as a pictogram. It is used for chemicals that can cause cancer, genetic defects, respiratory irritation, reproductive toxicity, organ toxicity and aspiration toxicity. There will only be one signal word on a chemical's label, no mat-ter how many different hazards the chemical may have. The HCS requires chemical … Health Hazard – The health hazard pictogram features a silhouette of a person with respiratory obstructions. Pictograms: These are graphic symbols used to communicate specific information about the hazards of a chemical. Period. These requirements impact chemical manufacturers, importers, and distributors. Classes 3 and 4: Flammable liquids and solids, Globally Harmonized System of Classification and Labelling of Chemicals, UN Recommendations on the Transport of Dangerous Goods, Federal Hazardous Materials Transportation Act, "Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006", https://en.wikipedia.org/w/index.php?title=GHS_hazard_pictograms&oldid=1007516142, Creative Commons Attribution-ShareAlike License, Miscellaneous dangerous substances and articles, the identity of the supplier (who might be a manufacturer or importer), Explosives, divisions 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, Self-reactive substances and mixtures, types A, B, Self-reactive substances and mixtures, types B, C, D, E, F, Self-heating substances and mixtures, categories 1, 2, Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3, e.g. Transport pictograms come in wider variety of colors and may contain additional information such as a subcategory number. Labels can help you identify the more hazardous chemicals, tell you what the hazards are and how to avoid … If you use a hazardous chemical, you should make sure that you use and dispose of it properly and know what to do if something goes wrong, like a spillage. Once a chemical leaves your facility it must have a GHS label. Telling others about the classification: the hazard label. The pictogram on the label is determined by the chemical hazard classification. 5 0 obj Enacted in 1975, the Hazardous Materials Transportation Act (HMTA) is … There are 7 distinct components of a chemical label. (TݺU(�d�?v?��؝Oǡ������7�a�O�����~/�8Z�|Q��?���i9/�i���k>��I��c?-�a8]���-�3������c�c-�/�ӥ�5���|��q8�H*-��8O��W���x��j���Ҵ��L�Az�^��8�Ȓ��|b\?iP�鈚�Ez�����6�B�颖�x4�T��g8�~1=����k�Xӽ�_DW�1`�ja=��X��$?��i`�t�!���8I�0^��,I�~� Symbols represent an idea that is conveyed using a picture without words. The product identifier for the Phenol, Chloroform & 3-methylbutan-1-ol mixture is “Phenol (50%), Chloroform (49%) & 3-methylbutan-1-ol (1%).” The product identifiers in the exam… WHMIS Symbols (previously referred to as WHMIS Pictograms) are a cornerstone of the WHMIS system. Manganese Heptoxide (fire diamond rating at health hazard is 4), Acute toxicity (oral, dermal, inhalation), category 4, Specific target organ toxicity following single exposure, category 3, with the "skull and crossbones" pictogram, the "health hazard" pictogram is used to indicate respiratory sensitization, Germ cell mutagenicity, categories 1A, 1B, 2, Reproductive toxicity, categories 1A, 1B, 2, Specific target organ toxicity following single exposure, categories 1, 2, Specific target organ toxicity following repeated exposure, categories 1, 2, Acute toxicity (oral, dermal, inhalation), category 5, Reproductive toxicity – effects on or via lactation, Acute hazards to the aquatic environment, category 1, Chronic hazards to the aquatic environment, categories 1, 2, Acute hazards to the aquatic environment, categories 2, 3, Chronic hazards to the aquatic environment, categories 3, 4, are ignitable when in a mixture of 13 percent or less by volume with air; or. More information about labelling small containers is available in the model Code of Practice: Labelling of Workplace Hazardous … 5101–5128) and D.O.T. @� �s��`n�7c��4���$� �,�8^�Zx9��I�3�]���z5Se�Uu��c����;\��^bW�Fڤ�>��-2)7M�Kz��� Hazard pictograms are one of the key elements for the labelling of containers under the GHS, along with:[2]. Pictograms are comprised of a hazard symbol with a red border to visually illustrate specific hazards of the chemical, making this a universally readable label. have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Prevent workplace injury and diseases by learning more about the pictograms. Either one or the other is chosen, depending on the target audience, but the two are not used together. Chemical products are used every day at work – not just in factories, but also in construction work or in offices – in things like cleaning products, paints, etc. A chemical label can have one or more pictograms on it. for placing the information also in a second language and/or for including further safety information etc., without the need to increase the size of the pictograms. a label, and describes what pictograms are and how to use them. Pictograms— onveys specific information about hazards of a chemical Hazard Statement— Describes the nature of hazards associated with a chemical D. First Aid Statement— Emergency care information E. Product Identifier— hemical … Just as a STOP sign instantly and accurately conveys the me… … The signal word that designates the highest level of hazard is the one that appears. 9 Hazard Communication Standard (HCS) Pictograms. The two sets of pictograms use the same symbols … In other words, if a chemical has a corrosion hazard that justifies a "Warning" signal word, but that same product also has a health hazard that requires a "Danger" signal word, the … Safe Work Australia’s Hazardous Chemical Information System 2. The minimum text size on the label is recommended to be about 1.8 mm (like that of Arial 7). regulations at 49 C.F.R. ... To create a product label, chemical manufacturers or importers/distributors are required to classify chemicals according to designated criteria that is outlined in appendices of the Hazard Communication Standard. Many chemicals can have a variety of different effects, in which case it is necessary to use two or more of these pictograms at the same time to alert people of the risk. There are various pictograms that can be included on the label, and depending on the chemical, a single label can contain more than one if the chemical has multiple hazards. on the hazard label and the chemical must be contained in packaging that meets the requirements of CLP.